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A large-scale synthesis process for perovskite quantum dots has been established.
September 12, 2017
By: DAVID SAVASTANO
Contributing Editor, Coatings World and Ink World
Quantum dots are extremely tiny nanoparticles typically between 10 to 10,000 atoms (1 to 9 nanometers) in diameter; they are thus smaller than 1/10,000th the width of human hair. Quantum dots are so small that they cannot be seen under a conventional microscope. However, the effects of this extreme small size cannot be ignored. Quantum dots are actually very powerful materials, and their size gives them unique abilities, including highly efficient conversion of light to nearly any color in the visible spectrum. The electronic characteristics of quantum dots are determined by the quantum confinement effect, in accordance with their chemical composition, size, and shape. This feature means that the color of light given off by a quantum dot can be controlled just by changing its size. Generally, larger dots emit light of longer wavelengths, such as red, while smaller dots emit light of shorter wavelengths, such as green or blue. The tune of a quantum dot is the wavelength of the light that it emits; this unique property can therefore be utilized for the following applications: • TV displays and smartphone displays. • Solar cells. • Security tags, security inks, and counterfeit protection devices. • Sensors. • Quantum dot lasers. • Quantum dot transistors. • Photonic crystals. • Bio-imaging, biomarkers, medical display applications (cancer cell imaging, protein analysis, and cell tracking). • High-density solid-material-based memory. • Thermoelectric materials. • Quantum dot computers. • Visible-light-response-type photocatalytic materials. • Artificial photosynthesis. • LEDs. Various types of quantum dots currently exist, but in general, they are made of semiconductor materials such as CdSe, CdS, InP, ZnS, InP/ZnS, CIS (CuInS2, CuInSe2), AgInS2 CIS/ZnS, and PbS, etc. Moreover, there are carbon, graphene, and silicon quantum dots. Fuji Pigment Co., Ltd. synthesizes and supplies all of these quantum dots. However, Cd-based quantum dots are toxic. In addition, indium is expensive and requires complete exclusion O2 and H2O, to synthesize InP. Set up of a manufacturing facility for these quantum dots is expensive. In this regard, Dr. Ryohei Mori at Fuji Pigment Co., Ltd. has been researching and developing a new type of quantum dots, perovskite quantum dots. The half width of their emission spectra is substantially narrower than that of InP; this property is very beneficial to the application of the dots in display materials, LED, bio-imaging. Since the half width of the dots is small, they can be utilized in displays, lasers, LED and bio-imaging. Fuji Pigment is trying to coat perovskite quantum dot surface with either polymer or inorganic materials, which would enhance the quantum dot resistance against water, light and heat. The Fuji Pigment Co., Ltd. is suggested to be the first company to commercialize perovskite quantum dots in the world.
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